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air pollution,contamination of the air by noxious gases and minute particles of solid and liquid matter (particulates) in concentrations that endanger health. The major sources of air pollution are transportation engines, power and heat generation, industrial processes, and the burning of solid wastesolid waste,
discarded materials other than fluids. In the United States in 1996, nearly 210 million tons—about 4.3 lb. (2 kg) per person daily (up from 2.7 lb./1.2 kg in 1960)—were collected and disposed of by municipalities.
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Sources of Air Pollution
The combustion of gasolinegasoline
light, volatile mixture of hydrocarbons for use in the internal-combustion engine and as an organic solvent, obtained primarily by fractional distillation and "cracking" of petroleum, but also obtained from natural gas, by destructive distillation
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self-propelled vehicle used for travel on land. The term is commonly applied to a four-wheeled vehicle designed to carry two to six passengers and a limited amount of cargo, as contrasted with a truck, which is designed primarily for the transportation of goods and
..... Click the link for more information. , trucks, and jet airplanes produces several primary pollutants: nitrogen oxides, gaseous hydrocarbons, and carbon monoxide, as well as large quantities of particulates, chiefly lead. In the presence of sunlight, nitrogen oxides combine with hydrocarbons to form a secondary class of pollutants, the photochemical oxidants, among them ozoneozone
, an allotropic form of the chemical element oxygen (see allotropy). Pure ozone is an unstable, faintly bluish gas with a characteristic fresh, penetrating odor. The gas has a density of 2.144 grams per liter at STP.
..... Click the link for more information. and the eye-stinging peroxyacetylnitrate (PAN). Nitrogen oxides also react with oxygen in the air to form nitrogen dioxide, a foul-smelling brown gas. In urban areas like Los Angeles where transportation is the main cause of air pollution, nitrogen dioxide tints the air, blending with other contaminants and the atmospheric water vapor to produce brown smogsmog
[smoke+fog], dense, visible air pollution. Smog is commonly of two types. The gray smog of older industrial cities like London and New York derives from the massive combustion of coal and fuel oil in or near the city, releasing tons of ashes, soot, and sulfur
..... Click the link for more information. . Although the use of catalytic converters has reduced smog-producing compounds in motor vehicle exhaust emissions, studies have shown that in so doing the converters produce nitrous oxide, which contributes substantially to global warmingglobal warming,
the gradual increase of the temperature of the earth's lower atmosphere as a result of the increase in greenhouse gases since the Industrial Revolution. Global warming and its effects, such as more intense summer and winter storms, are also referred to as climate
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In cities, air may be severely polluted not only by transportation but also by the burning of fossil fuels (oil and coal) in generating stations, factories, office buildings, and homes and by the incineration of garbage. The massive combustion produces tons of ash, soot, and other particulates responsible for the gray smog of cities like New York and Chicago, along with enormous quantities of sulfur oxides (which also may be result from burning coal and oil). These oxides rust iron, damage building stone, decompose nylon, tarnish silver, and kill plants. Air pollution from cities also affects rural areas for many miles downwind. In less developed regions, indoor air pollution from open fires burning wood and other fuels for heating and cooking can be a significant health hazard.
Every industrial process exhibits its own pattern of air pollution. Petroleum refineries are responsible for extensive hydrocarbon and particulate pollution. Iron and steel mills, metal smelters, pulp and paper mills, chemical plants, cement and asphalt plants—all discharge vast amounts of various particulates. Uninsulated high-voltage power lines ionize the adjacent air, forming ozone and other hazardous pollutants. Airborne pollutants from other sources include insecticidesinsecticides,
chemical, biological, or other agents used to destroy insect pests; the term commonly refers to chemical agents only. Chemical Insecticides
The modern history of chemical insecticides in the United States dates from 1867, when Paris green proved
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, chemical compound that kills plants or inhibits their normal growth. A herbicide in a particular formulation and application can be described as selective or nonselective.
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minute particles of radioactive material produced by nuclear explosions (see atomic bomb; hydrogen bomb; Chernobyl) or by discharge from nuclear-power or atomic installations and scattered throughout the earth's atmosphere by winds and convection currents.
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minute particles slowly settling or suspended by slight currents and existing in varying amounts in all air. There is least dust at high levels over the ocean and most at low levels over cities; dust from smoke is a serious urban problem (see air pollution).
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Effects on Health and the Environment
Like photochemical pollutants, sulfur oxides contribute to the incidence of respiratory diseases. Acid rainacid rain
or acid deposition,
form of precipitation (rain, snow, sleet, or hail) containing high levels of sulfuric or nitric acids (pH below 5.5–5.6).
..... Click the link for more information. , a form of precipitation that contains high levels of sulfuric or nitric acids, can contaminate drinking water and vegetation, damage aquatic life, and erode buildings. When a weather condition known as a temperature inversiontemperature inversion,
condition in which the temperature of the atmosphere increases with altitude in contrast to the normal decrease with altitude. When temperature inversion occurs, cold air underlies warmer air at higher altitudes.
..... Click the link for more information. prevents dispersal of smog, inhabitants of the area, especially children and the elderly and chronically ill, are warned to stay indoors and avoid physical stress. The dramatic and debilitating effects of severe air pollution episodes in cities throughout the world—such as the London smog of 1952 that resulted in 4,000 deaths—have alerted governments to the necessity for crisis procedures. Even everyday levels of air pollution may insidiously affect health and behavior. Indoor air pollution is a problem in developed countries, where efficient insulation keeps pollutants inside the structure. In less developed nations, the lack of running water and indoor sanitation can encourage respiratory infections. Carbon monoxide, for example, by driving oxygen out of the bloodstream, causes apathy, fatigue, headache, disorientation, and decreased muscular coordination and visual acuity.
Air pollution may possibly harm populations in ways so subtle or slow that they have not yet been detected. For that reason research is now under way to assess the long-term effects of chronic exposure to low levels of air pollution—what most people experience—as well as to determine how air pollutants interact with one another in the body and with physical factors such as nutritionnutrition,
study of the materials that nourish an organism and of the manner in which the separate components are used for maintenance, repair, growth, and reproduction. Nutrition is achieved in various ways by different forms of life.
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inhalation and exhalation of the fumes of burning tobacco in cigars and cigarettes and pipes. Some persons draw the smoke into their lungs; others do not. Smoking was probably first practiced by the indigenous peoples of the Western Hemisphere.
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in medicine, common term for neoplasms, or tumors, that are malignant. Like benign tumors, malignant tumors do not respond to body mechanisms that limit cell growth.
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abnormalities in physical or mental structure or function that are present at birth. They range from minor to seriously deforming or life-threatening. A major defect of some type occurs in approximately 3% of all births.
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in biology, a sudden, random change in a gene, or unit of hereditary material, that can alter an inheritable characteristic. Most mutations are not beneficial, since any change in the delicate balance of an organism having a high level of adaptation to its environment
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A relatively recently discovered result of air pollution are seasonal "holes" in the ozone layerozone layer
region of the stratosphere containing relatively high concentrations of ozone, located at altitudes of 12–30 mi (19–48 km) above the earth's surface.
..... Click the link for more information. in the atmosphere above Antarctica and the Arctic, coupled with growing evidence of global ozone depletion. This can increase the amount of ultraviolet radiation reaching the earth, where it damages crops and plants and can lead to skin cancerskin cancer,
malignant tumor of the skin. The most common types of skin cancer are basal cell carcinoma, squamous cell carcinoma, and melanoma. Rarer forms include mycosis fungoides (a type of lymphoma) and Kaposi's sarcoma.
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in medicine, opacity of the lens of the eye, which impairs vision. In the young, cataracts are generally congenital or hereditary; later they are usually the result of degenerative changes brought on by aging or systemic disease (diabetes).
..... Click the link for more information. . This depletion has been caused largely by the emission of chlorofluorocarbons (CFCs) from refrigerators, air conditioners, and aerosols. The Montreal ProtocolMontreal Protocol,
officially the Protocol on Substances That Deplete the Ozone Layer, treaty signed on Sept. 16, 1987, at Montreal by 25 nations; 197 nations are now parties to the accord.
..... Click the link for more information. of 1987 required that developed nations signing the accord not exceed 1986 CFC levels. Subsequent meetings have adopted amendments to the protocol to accelerate the phasing out of ozone-depleting substances.
Solutions to Air Pollution
To combat pollution in the United States, the Clean Air Act Amendments of 1970 gave the Environmental Protection Agency (EPA) the authority to establish and enforce air pollution standards and to set emission standards for new factories and extremely hazardous industrial pollutants. The states were required to meet "ambient air quality standards" by regulating the emissions of various pollutants from existing stationary sources, such as power plants and incinerators, in part by the installation of smokestack scrubbers, electrostatic precipitators, and other filters. Auto manufacturers were mandated to install exhaust controls or develop less polluting engines. The Clean Air Act, as amended in 1977, authorized the EPA to impose stricter pollution standards and higher penalties for failure to comply with air quality standards.
In 1990 when the act was reauthorized it required most cities to meet existing smog reduction regulations by the year 2005. The 1990 amendments also expanded the scope and strength of the regulations for controlling industrial pollution. The result has been limited progress in reducing the quantities of sulfur dioxide, carbon monoxide, nitrogen oxide, ozone, particulate matter, and lead in the air. The EPA also regulated hazardous air pollutants, which in 1992 included mercury, beryllium, asbestos, vinylchloride, benzene, radioactive substances, and inorganic arsenic.
The most satisfactory long-term solutions to air pollution may well be the elimination of fossil fuels and the ultimate replacement of the internal-combustion engineinternal-combustion engine,
one in which combustion of the fuel takes place in a confined space, producing expanding gases that are used directly to provide mechanical power.
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origins of the power used for transportation, for heat and light in dwelling and working areas, and for the manufacture of goods of all kinds, among other applications.
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or emission rights,
government-issued permit to emit a certain amount of a pollutant. The holder of the permit may use it to pollute legally, may trade permits, or may sell the permit for a profit.
..... Click the link for more information. based on trading emission rights has been established in the United States in an attempt to use the free market to reward pollution reductions, and the international sale of surplus emission rights is permitted under the Kyoto Protocol (see below). Other proposed solutions include raising electricity and gasoline rates to better reflect environmental costs and to discourage waste and inefficiency, and mechanical controls on coal-fired utility plants.
In 1992, 150 nations signed a treaty on global warming at the UN-sponsored summit on the environment in Rio de Janeiro. A UN Conference on Climate Change, held in Kyoto, Japan, in 1997, produced an international agreement to combat global warming by sharply reducing emissions of industrial gases produced by industrialized nations. Although the United States abandoned the treaty in 2001, saying it was counter to U.S. interests, most other nations agreed that year on the details necessary to make the protocol a binding international treaty, and the necessary ratifications brought the treaty into force in 2005. Efforts to develop a new, more encompassing binding treaty that would build on the Kyoto Protocol were long unsuccessful, and in 2012 Canada became the first ratifying nation to withdraw. Later in 2012 the Kyoto Protocol was extended to 2020. In 2015, however, the world's nations agreed for the first time to take measures to hold global warming below 3.6°F; (2°C;), and all parties, not just developed nations, agreed to reduce emissions; a revision of emissions targets (beginning in 2020) and a review of actual emission reductions (beginning in 2023) were required every five years. U.S. support for the 2015 agreement, however, reversed with the election (2016) of Donald Trump as president; he moved to dismantle federal policies intended to address climate change and announced the United States would withdraw from the agreement.
movement to protect the quality and continuity of life through conservation of natural resources, prevention of pollution, and control of land use. The philosophical foundations for environmentalism in the United States were established by Thomas Jefferson,
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contamination of the environment as a result of human activities. The term pollution refers primarily to the fouling of air, water, and land by wastes (see air pollution; water pollution; solid waste).
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See R. G. Bond et al., Air Pollution (1972); U.S. Council on Environmental Quality, Environmental Quality (22d Annual Report, 1991); World Bank, World Development Report (1992).