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Related to Aldehydes: Carboxylic acids



a class of organic compounds that contain a carbonyl group Aldehydes combined with an organic radical (R) and a hydrogen atom, Aldehydes. The properties of aldehydes are in many respects similar to those of ketones; the latter also contain a carbonyl group, but it is combined with two radicals, R2CO. The names of aldehydes are usually derived from the names of the corresponding acids. Thus, formaldehyde (HCHO) corresponds to formic acid (HCOOH) and acetaldehyde (CH3CHO) corresponds to acetic acid.

Comparison of the formulas of alcohols (RCH2OH), aldehydes (RCHO), and acids (RCOOH) shows that the aldehydes occupy an intermediate position among them in their degree of oxidation. Some of their methods of preparation and chemical properties are related to this. Thus, oxidation of primary alcohols or careful reduction of acid chlorides yields aldehydes


RCOC1 + H2 → RCHO + HCl

The intermediate position of the aldehydes is also manifested in their ability to undergo oxidation-reduction reactions; for example, in the presence of an alcoholic solution of a caustic alkali, aldehydes are transformed into a mixture of alcohol and acid


Aldehydes can also be obtained by the pyrolysis of mixed calcium salts of formic acid and some other carboxylic acid


Aromatic aldehydes are prepared by the careful oxidation of aromatic compounds containing a methyl group

The analogous procedure for preparing acrolein—the simplest unsaturated aldehyde—from propylene is commercially important

An industrially important synthesis of acetaldehyde involves the hydration of acetylene in the presence of mercury salts

HC ≡ CH + H20 → CH3CHO

Aldehydes have a tendency to polymerize—for example, formaldehyde is easily transformed into paraformaldehyde and acetaldehyde into the cyclic trimer paraldehyde. The condensation of 2 moles of aldehyde yields aldols


which with the separation of water form unsaturated aldehydes


Aldehydes readily enter into many addition and substitution reactions. For example, with HCN they form cy-anohydrins: RCH(OH)CN. Analogously, they react with sodium bisulfite, amines, and other substances. With hydroxylamine or hydrazines, aldehydes yield oximes (RCH=NOH) and hydrazones (RCH=N—NH2), respectively.

Aldehydes are widely used in the production of phenol-aldehyde resins, as aromatic substances (vanillin, citral, and others), and as intermediaries in the synthesis of other substances. For example, CH3CHO is used in the synthesis of acetic acid (CH3COOH) and ethyl acetate (CH3COOC2H5). Aldehydes are also used in the synthesis of olefins and polyenes.


References in periodicals archive ?
Figure 2 illustrates the alteration of VOC composition among terpenes (green) and aldehydes (red) throughout the experiment.
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Subset libraries include: Polymers and Polymer Additives; Dyes, Pigments, and Stains; Hazardous and Toxic Chemicals; Organometallics and Inorganics; Solvents; Biochemicals; Aldehydes and Ketones; Alcohols and Phenols; Esters, Lactones, and Anhydrides; Semiconductor Chemicals; Sulfur and Phosphorus Compounds; Hydrocarbons; Food Additives and Food Packaging; Forensics; Pesticides; and Flavors, Fragrances, and Cosmetics.
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