There are five main minima under zero point line (dash line) for (1) the free carbonyl of MMA units at 1730 [cm.sup.-1] (the adsorption of MMA units hydrogen-bonded to
amide groups is shown as a shoulder at 1720 [cm.sup.-1]), (2) the free amide I groups of MAAM units at 1681 [cm.sup.-1], (3) the amide I groups of MAAM hydrogen bonding intermolecularly to the carbonyl groups of MMA (HB amide I in Fig.
Glass transition and [alpha] relaxation temperatures ([T.sub.g], [T.sub.[alpha]])of dry and solvent-saturated PA66 samples and mass intake [DELTA] m (referred to the total PA66 mass) and molar intake [DELTA] n (referred to the amount of
amide groups in the amorphous phase) of the studied solvents at room temperature (20 [degrees] C).
On the other hand, [beta]-transition is attributed to the segmental motion that involves the
amide groups in amorphous regions, which are not bonded by hydrogen bonds to other amides or a nearby chain.
Among other properties of resulted PEAs, the dielectric ones must take into consideration for investigation being known that the polar
amide groups containing in the macromolecular chains and reorientation motions of corresponding dipoles are sensitive to the electric stimulus [3,20].
The hypothesis in this work was that since each urea molecule contains four hydrogens and can establish strong intermolecular interactions (H-bonding) with the
amide groups in the PA, it can disrupt the intermolecular interactions (hydrogen bonding) among the polymer chains, therefore resulting in an easier dissolution.
Essentially the free radical attacks a double bond on a monomer and the electron moves on to another monomer, the process is continued until the end result is a chain of cyclic
amide groups which is attached to the hydrophobic back bone [11].
The [sup.1]H NMR spectra showed one signal for the
amide group hydrogen as a triplet or singlet between 10.60 and 8.53 ppm.
The [sup.13]C NMR spectrum of 7 contains peaks at 19.20 ppm for methyl group bound to steroid nucleus; at 26.70-48.94, 114.18-114.70, 124.70, 134.10, and 139.72-154.78 ppm for steroid moiety; at 110.80, 118.22120.90, and 134.78 ppm for indole group; at 115.22, 123.45, 125.60-132.50, and 163.80 ppm for benzoyl azide group; and at 171.52 ppm for
amide group. Finally, the presence of compound 7 was further confirmed from mass spectrum which showed a molecular ion at m/z 488.20.
The addition of various lipophilic aliphatic and aromatic groups had little effect on increasing potency of clicked compounds, while exchanging the ester group for an
amide group (compounds 16a-h), which had shown to have important influence on inhibition in previous studies [26], had very little effect on potency.
has been granted a patent for a powder coating composition, which contains a macromolecule compound (A) having
amide group and/or imide group, an anti-oxidizing material (B) and a fluororesin (C), wherein the macro-molecule compound (A) has an average particle size of 45 [micro]m or less, wherein the macromolecule.
Keywords Anhydride group,
Amide group, Cellulose, Cotton, Infrared spectroscopy, Soybean oil
This group is called an
amide group (in most of the world nylons are called polyamides) and it is responsible for the relatively high melting point, strength, and affinity for moisture that nylons exhibit.
