Bakelite


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Bakelite

(bā`kəlīt) [for its inventor, L. H. BaekelandBaekeland, Leo Hendrik
, 1863–1944, American chemist, b. Belgium, grad. Univ. of Ghent, 1882. In 1889 he emigrated to the United States. He founded (1893) and conducted, until 1899, when he sold the rights to Eastman, a company for producing a photographic paper of his own
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], synthetic thermosetting resinresin,
any of a class of amorphous solids or semisolids. Resins are found in nature and are chiefly of vegetable origin. They are typically light yellow to dark brown in color; tasteless; odorless or faintly aromatic; translucent or transparent; brittle, fracturing like glass;
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. It has been widely used both alone, to form whole objects, and in combination with other materials, as a laminate or a surface coating. It was used as a substitute for hard rubber, amber, or celluloid; for insulating electrical apparatus (since it is a nonconductor); and for the manufacture of certain machinery gears, phonograph records, and many other articles useful and ornamental and as diverse in character as buttons, billiard balls, pipestems, and umbrella handles. Bakelite is a condensation polymerpolymer
, chemical compound with high molecular weight consisting of a number of structural units linked together by covalent bonds (see chemical bond). The simple molecules that may become structural units are themselves called monomers; two monomers combine to form a dimer,
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 of formaldehydeformaldehyde
, HCHO, the simplest aldehyde. It melts at −92°C;, boils at −21°C;, and is soluble in water, alcohol, and ether; at STP, it is a flammable, poisonous, colorless gas with a suffocating odor.
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 and phenolphenol
, C6H5OH, a colorless, crystalline solid that melts at about 41°C;, boils at 182°C;, and is soluble in ethanol and ether and somewhat soluble in water. An aromatic alcohol, it exhibits weak acidic properties and is corrosive and poisonous.
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. In practice, the phenol and formaldehyde are first polymerized to a small extent by using the proper choice of catalyst and temperature. The resulting prepolymer, called a resol, is a low-melting, soluble material, which can then be combined with a filler (usually cotton linters or wood fibers) and a pigment and heated under pressure in a mold to yield an object of the desired shape. The pure resin is colorless or amber-colored and very brittle; the various fillers and other additives give it the desired properties depending on its application. Heating of the prepolymer results in extensive cross-links between the polymer chains, resulting in a tightly bound three-dimensional network. A Bakelite-type resin can also be formed using furfuralfurfural
or furfuraldehyde
[Lat.,=bran], C4H3OCHO, viscous, colorless liquid that has a pleasant aromatic odor; upon exposure to air it turns dark brown or black. It boils at about 160°C;.
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 in place of the formaldehyde.

Bakelite

™ any one of a class of thermosetting resins used as electric insulators and for making plastic ware, telephone receivers, etc
References in periodicals archive ?
Old Bakelite phones <Btransformed into lights make a design statement and are simply good fun and real talking points
In fact, some of the doorknobs in our house are made of Bakelite.
Prices start at just a few pounds for a small bakelite brooch and can go into the low hundreds for a particularly stylish bakelite necklace, more if it is by a well known designer.
They sell and are always looking for Bakelite and celluloid pieces.
The next presentation was by Keith Parsons who spent 25 of his 32 years career in R&D at Bakelite developing both industrial and decorative laminates, much of the time as technical manager of the Warerite Division.
Baekeland's first intended use of Bakelite was for phonograph records, but he quickly realized that there were other possibilities, so it was soon marketed as "The Material of a Thousand Uses.
Phenolic molding compounds developed by the Sumitomo Bakelite Group have great advantages such as superior heat insulation, high mechanical strength, weight reduction, and corrosion resistance with an overall price performance.
I CAN REMEMBER the day, when I was just tall enough to see the top of the kitchen table, that my father patiently assembled a crystal radio set: a shoebox, the tube out of a toilet roll, wound with copper wire, a few bakelite knobs and the whiff of melting solder.
The new Hexion Specialty Chemicals also includes Bakelite AG, a company that Borden Chemical previously announced they would be acquiring.
Hexion also includes Bakelite AG, which Borden Chemical acquired in late April.
Sumitomo Bakelite to buy overseas phenolic molding compound firms