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Manganese(II) nitrate-tetrahydrate (97%), zirconium nitrate (99%), sodium bicarbonate (99%), toluene (98%), benzyl alcohol (99.5%), biphenyl-4-methanol (98%), 2-phenylethanol (98%), furfuryl alcohol (98%), cinnamyl alcohol (98%), diphenylmethanol (99%), 4-chlorobenzhydrol (98%), 1-phenylethanol (98%), 1-(4-chlorophenyl)ethanol (98%), 1-phenyl-2-propanol (98%), 4-phenyl-2-butanol (97%), cyclohexanemethanol (99%), 1-octanol (99%), 5hexen-1-ol (98%), [beta]-citronellol (98%), cyclohexanol (99%), 3-buten-2-ol (97%), and 2-octanol (99%) were purchased from Sigma Aldrich, St.
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ENTRY Alcohol Conversion Yield Selectivity (c) [%] (c) [%] (c) [%] 1 (a) Benzyl alcohol
99 99 99.0 2 (a) 4-Chlorobenzyl 98 98 98.0 alcohol 3 (a) 4-Methoxylbenzyl 99 84.8 85.6 alcohol 4 (a) 4-Phenyl-2-butanol 99 95.1 96.1 5 (b) Benzyl alcohol
99 96.9 97.8 6 (b) 4-Chlorobenzyl 99 83.1 84.0 alcohol 7 (b) 4-Methoxylbenzyl 99 99 99.0 alcohol (a) Alcohol (1 mmol) in DCM, potassium bromide solution (1.0 M, 1 mL), 4-methoxyacetophenone (208.0 mg, internal standard), and TEMPO-MNPs (150 mg) were added to a round-bottom flask.