argentatum, negative cooperativity inhibits the chain transfer reaction
across a wide range of FPP concentrations, a property possessed in far less degree by H.
In addition, the simple bridge alteration affects the chain transfer reaction
and the distribution of the 1-decene along the copolymer chain.
The free-radical reactions leading to SCB and LCB and involving polymer growing radicals are in competition either with chain propagation or with chain transfer reaction
to a selected added molecule.
In order to study the importance of the chain transfer reaction
we also run the model using the kinetic parameters of the reduced mechanism (RM; see Table 6) where the above mentioned reaction is not included.
In this case, the NMR analysis identified the formation of morpholine end groups arising from the attack of neighboring hydroxyl groups, which possibly correspond to the main chain transfer reaction
Then, the chain transfer reaction
of propagating radical with PEPDTA may occur and form dormant chain by addition fragmentation.
Finally, the chain transfer reaction
is assumed to occur spontaneously or through the reaction of active chain with hydrogen, monomer, and/or cocatalyst.
Chain transfer reaction
does not change the number of total active sites, but changes the number of the active sites with different chain lengths, and we consider only the first-order transfer reaction of active sites and the transfer reaction to monomer.
This initiator was chosen because it does not present chain transfer reaction
during polymerization (18).
When the polymer is essentially linear and average chain size is controlled mainly by chain transfer reactions
It has been suggested that the loss in scorch safety is primarily attributed to the elimination of degradative chain transfer reactions
as the groups of Type I coagents quickly react with the alkoxy radical and do not possess an allylic hydrogen.
RC-le as a Tool to Monitor Chain Transfer Reactions
in Emulsion Polymerization" -- Stacy Stromeyer, Carolina Quintero, David Delatte, James W.