The influence of micro-waves on stereo selectivity, regioselectivity and chemoselectivity
along with the enormous accelerations resulting in speedy molecular interactions causing higher yield and purity as well are attributes that cannot be overlooked without contemplation (Jayabharathe et al., 2015).
in the reduction of aldehydes and ketones with amine boranes," Tetrahedron Letters, vol.
toward Mono-N-methylation," Journal of Organic Chemistry, vol.
In order to achieve high chemoselectivity
in a subsequent chemical reaction, it is necessary to use protecting groups.
Wee, "Conformational, steric and electronic effects on the site- and chemoselectivity
of the metal-catalyzed reaction of N-bis(trimethylsilyl)methyl, N-(2indolyl)methyl a-diazoamides," Organic & Biomolecular Chemistry, vol.
They can catalyze alcohols to the corresponding aldehydes/ketones in high yield and with chemoselectivity
[34, 35, 38-40].
The first chapter discusses the modes of selectivity: chemoselectivity
, regioselectivity, stereoselectivity, and enantioselectivity, with examples and comments on synthetic strategy.
This observation led us further to the study on chemoselectivity
aspects from reduction process.
The energy diagram for the reaction pathway is in agreement with the experimental conditions that favor the observed chemoselectivity
and high yields.
Mohsenzadeh, "Synthesis of 1,n-acyloxy thioamides by the Willgerodt-Kindler reaction: chemoselectivity
of 1,3-ketoesters over 1,3-diketones," Zeitschrift fur Naturforschung, vol.
FANCF methylation contributes to chemoselectivity
in ovarian cancer.