The combination reported here of racemic signatures in dust and diet suggests that the directionally consistent and non-racemic signatures for [alpha]-HBCD in serum are attributable to enantioselective
metabolism and/ or excretion as opposed to external exposure to nonracemic matrices.
The molecular imprinting technology offers a unique possibility of obtaining MIPs with predetermined enantioselective
binding properties for given chiral targets [42,43].
160 LEUTENEGGER U,TETRAHEDRON,vol 0048,page 2143,1992,cites= 27,5 -AZA-SEMICORRINS - A NEW CLASS OF BIDENTATE NITROGEN LIGANDS FOR ENANTIOSELECTIVE
Progress towards the enantioselective
total synthesis of hamiger-omycin b: part I, preparation of the polyketide synthon.
Alfred Bader Award for his work on the development of enantioselective
synthetic methods, bacterial dioxygenase-mediated degradation of aromatics, design and synthesis of fluorinated inhalation anesthetic agents, synthesis of morphine and amaryllidaceae alkaloids and their medicinally useful derivatives, and design of unnatural oligo-saccharide conjugates with new molecular properties.
Negative-ion chemical ionization gas chromatography-mass spectrometry assay for enantioselective
measurement of amphetamines in oral fluid: application to a controlled study with MDMA and driving under the influence cases.
An appendix is also supplied that provides terms and enantioselective
processes in asymmetrical catalysis.
11:15 EXO-AND ENANTIOSELECTIVE
DIELS ALDER REACTIONS:
synthesis of the female sex pheromone of the pink hibiscus mealybug, Maconellicoccus hirsutus.
oxidation of amphetamine by copper-containing quinoprotein amine oxidases from Escherichia coli and Klebsiella oxytoca.
metabolism of the endocrine disruptor pesticide methoxychlor by human cytochromes P450 (P450s): major differences in selective enantiomer formation by various P450 isoforms.
This volume features a comprehensive treatment of transition metal (palladium, nickel, copper) catalyzed a-arylation of enolates derived from many common functional groups such as ketones, aldehydes, esters and nitriles (Prim, Marque, Gaucher, Campagne) including enantioselective
variants; palladium catalyzed cyclization to form indoles (Cacchi, Fabrizi, Goggiamani) one of the most prevalent and important classes of heterocycles in natural products and pharmaceutical agents; and an overview of a newly developed dihydroxylation reaction of alkenes (Donohoe, Bataille, Innocenti) that uses hydrogen bonding interactions to direct the delivery of an osmium catalyst with high selectivity.