from 1-indanone (generated in homogeneous phase, using LDA as the base) reacted with the methylsulfinyl chloride to form the keto sulfoxide in one step .
It may be assumed that the oxidation occurs via an intermediate enolate
giving rise to an allylic structure.
and Chelate Enolate
Iron and cerium enolates
in a concentration of 3-200 ppm are patented as combustion improving additives .
Ian Paterson described the synthesis of complex acyclic and macrocyclic polypropionate derived-natural products based on optimized strategies for stereoselective formation of syn-syn and anti-syn aldol adducts using tin and boron enolates
The remaining 12 chapters are presented in the same thorough, clearly organized format, with topics that include structural organomanganese chemistry, structures and reaction mechanisms of manganese oxidants, organomangenese-mediated radical reactions, and the chemistry of manganese enolates
They also cover nucleic substitution at aliphatic carbon, synthesis of epoxides and aziridines, the protonation of enolates
and kinetic resolution of racemic alcohols and amines.