Toluidine
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Related to M-toluidine: Para-toluidine, 4-methylaniline
The following article is from The Great Soviet Encyclopedia (1979). It might be outdated or ideologically biased.
Toluidine
any of three amino derivatives of toluene.
Ortho, meta, and para isomers of toluidines are known (see Table 1). Toluidines are readily soluble in organic solvents but poorly soluble in water; they may be steam-distilled, and they darken (oxidize) upon storage in light in the presence of air.
Toluidines are obtained industrially by the reduction of nitro-toluenes using iron and hydrochloric acid. They are similar to aniline in their chemical properties. They form salts with acids and
Table 1. Selected properties of toluidines | |||
---|---|---|---|
Melting point (°C) | Boiling point (°C) | Density at 20°C (g/cm3) | |
Ortho-toluidine(1,2-). . . . . . . . . . | –24,4 (unstable) | 200.3 | 0.9984 |
Ortho-toluidine (1,6-). . . . . . . . . . | –16.25 (stable) | 200.3 | 0.9984 |
Mete-toluidine(1,3-or 1,5-). . . . . . . . . . | –30.4 | 203.4 | 0.9891 |
Para-toluidine (1,4-). . . . . . . . . . | 44.5–45,0 | 200.55 | 1.046 |
undergo diazotization, acylation, halogenation, sulfonation, and alkylation. Toluidines are used in the manufacture of various dyes.
B. L. DIATKIN
The Great Soviet Encyclopedia, 3rd Edition (1970-1979). © 2010 The Gale Group, Inc. All rights reserved.