Natural Arsenates

The following article is from The Great Soviet Encyclopedia (1979). It might be outdated or ideologically biased.

Natural Arsenates

 

a group of minerals; salts of or-thoarsenic acid with different cations—Ca, Mg, Cu, Pb, Ni, Co, Fe, and others. They are crystallochemically related to the carcasslike, islandlike, chain, and laminated types of structure. All the minerals of the group natural arsenates are divided according to their chemical composition into anhy-drates (mimetesite Pb5(AsO4)3Cl, olivenite Cu2(AsO4)OH) and hydrates (annabergite Ni3(AsO4)2 8H2O, erythrite Co3(AsO4)2 8H2O, and scorodite Fe(AsO4) 2H2O). The natural arsenates crystallize most frequently in the lower systems—rhombic and triclinic—more rarely in hexagonal and trigonal systems, and very rarely in a cubic system. The natural arsenates form fine crystals; the most characteristic forms of deposits are accumulative and earthy masses. The density of the anhydrate natural arsenates is 7,190–7,250 kg/m3; of the hydrates, 2,950–3,300 kg/m3. Their hardness on the mineralogical scale is 2.5–5.5. The natural arsenates are formed during exogenic processes, usually in the oxidation zone of sulfide deposits. Many natural arsenates have industrial significance as ores of different metals.

REFERENCE

Mineraly: Spravochnik, vol. 1. Moscow, 1960.

A. B. PAVLOVSKII

The Great Soviet Encyclopedia, 3rd Edition (1970-1979). © 2010 The Gale Group, Inc. All rights reserved.