Nitrogenous Fertilizers

Nitrogenous Fertilizers

 

mineral and organic substances used as a source of nitrogen nutrition for plants. They are divided into organic fertilizers (manure, peat, compost) containing other nutrients besides nitrogen; manufactured mineral fertilizers; and green fertilizers (lupine, serradella).

Nitrogenous fertilizers were used in very ancient times. Manure was extensively used in ancient Rus’. Green fertilization has long been known in the irrigated agriculture of Middle Asia. Mineral fertilizers came into use much later. The first was sodium nitrate, obtained since the middle of the 19th century from natural deposits in Chile (South America); its consumption in 1900 was about 300,000 tons (converted into nitrogen). In the next years industry began to produce ammonium sulfate, calcium cyanamide, and calcium nitrate.

By 1913 world production of nitrogenous fertilizers was almost 700,000 tons (converted to nitrogen). Synthesizing ammonia from atmospheric nitrogen and hydrogen on an industrial scale (1914–1918) made a sharp boost in world production of nitrogenous fertilizers possible; production rose in 1966 to 19,200,000 tons (converted to nitrogen), including 6,400,000 in the United States, 1,449,000 in the Federal Republic of Germany, 1,082,000 in France, 462,000 in Poland, and 343,000 in the German Democratic Republic.

Russia produced 3,000 tons (converted to nitrogen) in 1913. A large nitrogenous fertilizer industry came into being during the first five-year plan. Agriculture was supplied with nitrogenous fertilizers (converted to nitrogen) as follows: 2,000 tons in 1928, 199,000 tons in 1940, 75,000 tons in 1945, 307,000 tons in 1950, 1,003,000 tons in 1960, 2,712,000 tons in 1965, 3,188,000 tons in 1966, 3,753,000 tons in 1967, and 4,177,000 tons in 1968. Mineral nitrogenous fertilizers may contain nitrogen in ammonia (NH3), ammonium nitrate (NH3 and NO3), nitrate (NO3), and amide (NH2) forms.

Ammonia fertilizers Ammonia fertilizers include ammonium sulfate, ammonium chloride, ammonium bicarbonate, and liquid nitrogenous fertilizers. Ammonium sulfate and ammonium chloride are most effective on base-saturated soils (chernozems, calcareous serozems, chestnut) which can neutralize their acidifying effect. Systematic fertilization with ammonium sulfate or ammonium chloride increases soil acidity, which can be corrected by liming. Ammonia nitrogen is less susceptible to leaching than nitrate nitrogen; thus, ammonia fertilizers can be added in the fall, before planting. They are less suitable for surface (as supplementary feeding for winter crops) and local (in rows or by cluster sowing) application. Excessive chlorine in ammonium chloride has an adverse effect on the size and quality of the yield of many crops, including potatoes, flax, oil-producing plants, tobacco, and grapes. Ammonium bicarbonate, still produced only in limited quantities for experimental purposes, has an alkaline reaction, but it undergoes nitrification in soil. Among the ammonia forms, liquid fertilizers—liquid anhydrous ammonia, aqua ammonia, and ammoniates—are the most important.

Ammonium nitrate fertilizers Ammonium nitrate fertilizers include ammonium nitrate and ammonium nitrosulfate (leuna saltpeter, ammonium sulfate-nitrate). Ammonium nitrate is produced chiefly in pellet form; it acidifies the soil slightly. Ammonium nitrosulfate has a comparatively high acidifying capacity.

Nitrate fertilizers Nitrate fertilizers include sodium nitrate (Chilean saltpeter), calcium nitrate (lime saltpeter, Norwegian saltpeter), and potassium nitrate. Sodium nitrate is physiologically alkaline and is therefore best applied to acid soils, especially when sugar beets, wheat, barley, and other acid-sensitive crops are grown. Calcium nitrate is put up in pellets usually admixed with ammonium nitrate; it, too, alkalizes the soil. Potassium nitrate contains potassium as well as nitrogen and is a source of nitrogen-potassium nutrition for plants. It is applied to chlorine-sensitive crops. All the nitrate forms of nitrogen are not absorbed by the soil. In regions with excess moisture, nitrate fertilizers are leached out of light soils with weak water-retention capacity. It is best, therefore, to use ammonia fertilizers as the main fertilizers.

Amide fertilizers Amide fertilizers include urea (carbamide), calcium cyanamide, and urea-formaldehyde. Urea is the most valuable. In soil it readily changes into ammonium carbonate; it first slightly alkalizes the soil and then weakly acidifies it. It is recommended that urea be added early. It is also used as a protein supplement for ruminants. Calcium cyanamide is able to reduce soil acidity.

Table 1. Properties of the main mineral nitrogenous fertilizers
 Chemical formulaAverage nitrogen content (in percent)Fertilizer mass by volume (kg/m3)Drillability after storageTendency to cakeHygroscopicity
Ammonium sulfate.....(NH1)2S0420.5–21.5800good (with moisture contentslightvery weakno more than 2%)slightvery weak
Ammonium chloride . . .NH2CL26.0600satisfactorymoderatslight
Anhydrous ammonia ...NH382.3620
Aqua ammonia........NH3 + H2O20.0910
Ammonium nitrate
granulated..........NH1 NO334.7–35.0820goodslightvery strong
crystalline ..........NH1NO334.7–35.0840poorstrongvery strong
Sodium nitrate........NaNO316.01,100–1,400satisfactoryslightmoderate
Calcium nitrate ......Ca(NO3)2 • 2H2017.0900–1,100satisfactorystrongvery strong
Urea
granulated..........(NH2)2CO46.0650gooddoes not cakevery weak
crystalline ..........(NH2)2CO46.0650poorslightvery weak

If applied in the fall, it is effective on mellow neutral soils rich in organic matter. It is unsuitable for local application. Calcium cyanamide is also used as a defoliant to remove leaves from cotton before it is harvested. Urea-formaldehyde fertilizers are not leached out of the soil and are especially effective in regions of excess moisture and irrigated agriculture. The use of large amounts provide crops with enough nitrogen to last several years. The characteristics of mineral nitrogenous fertilizers are given in the table.

Nitrogenous fertilizers are an effective means of increasing crop productivity, especially in the nonchernozem zone, humid regions of the forest steppe, and the zone of irrigated agriculture where the soils do not contain enough nitrogen. The fertilization rates vary with soil conditions, biological characteristics of the crops, and available supply of manure or other organic fertilizers. The approximate rates of nitrogenous fertilizers (in kg per ha converted into nitrogen) are 40–60 for winter grains sown after an occupied fallow and 30–40 after a clean fallow; 40–60 for spring grains; 60–120 for silage corn and for grain in the nonchernozem zone and northern part of the forest-steppe zone, 45–60 on rich chernozems of the forest steppe, and 120–150 in irrigated regions; 45–60 for sugar beets on chernozems of the forest steppe, 80–120 on gray forest soils, podzolized chernozems of the forest steppe, and in the nonchernozem zone, and 100–150 in irrigated regions; 120–140 for cotton; 40–60 for fiber flax; 45–90 for hemp; 45–90 for potatoes; 90–120 for cabbage; 60–90 for tomatoes and cucumbers; 60–100 for fruits and berries.

Smaller amounts are applied to soils richer in natural nitrogen or when manure or other nitrogen-containing organic fertilizers are used at the same time. If nitrogenous fertilizers are in ample supply, the rates can be increased in humid regions; this generally increases the yield and improves the quality of the crops. For example, good nitrogen nutrition favors the formation of gluten in wheat grain and increases the protein content of fodder crops.

Nitrogenous fertilizers are used as the base fertilizer and as supplementary feeding. They are added to winter crops which were sown after a clean fallow only as early spring supplements (30–40 kg of nitrogen per ha) on semithawed soil (on the ground’s ice “crust”). In all zones of the USSR, it is useful to add nitrogenous fertilizers at the full rates to spring crops before sowing and, if the crops are to be irrigated, in stages before irrigation. Cotton is fertilized three times: before sowing, at the start of budding, and at the start of flowering (one-third of the rate at a time).

REFERENCES

Spravochnik po mineral’nym udobreniiam. Edited by M. V.Katalymov. Moscow, 1960.
Tekhnologiia mineral’nykh solei, 2nd ed. Leningrad, 1961.
Prianishnikov, D. N. Izbr. soch., vol. 1. Moscow, 1963.
Spravochnik po udobreniiam, 3rd ed. Moscow, 1964.

F. V. TURCHIN

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