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A measure of the width of the band of frequencies of radiation emitted or absorbed in an atomic or molecular transition. One of the dominant sources of electromagnetic radiation of all frequencies is transitions between two energy levels of an atomic or molecular system. The frequency of the radiation is related to the difference in the energy of the two levels by the Bohr relation (1),

where ν0 is the frequency of the radiation, h is Planck's constant, and E1 and E2 are the energies of the levels. This radiation is not monochromatic, but consists of a band of frequencies centered about ν0 whose intensity I(ν) can be characterized by the linewidth. The linewidth is the full width at half height of the distribution function I(ν). The simplest case is for a transition from an excited state to the ground state for an atom or molecule at rest. For this case, the normalized distribution function is the lorentzian line profile given by Eq. (2).
Here Δν is the full width at half maximum (FWHM). The FWHM is related to the lifetime τ of the excited level through Eq. (3).
This is a manifestation of the quantum-mechanical uncertainty principle, and the linewidth Δν is referred to as the natural linewidth. See Energy level (quantum mechanics), Quantum mechanics, Uncertainty principle

Another major source of line broadening for atomic and molecular transitions is the Doppler shift due to thermal motion. For most situations the Doppler width is greater than the natural linewidth. See Doppler effect

A third major source of line broadening is collisions of the radiating molecule with other molecules. This broadens the line, shifts the center of the line, and shortens the lifetime of the radiating state.

For radiating atoms in a liquid or solid the width is usually dominated by the strong interaction of the radiator with the surrounding molecules. The net result is a broad line profile with a complex structure. See Band theory of solids


(atomic physics)
A measure of the width of the band of frequencies of radiation emitted or absorbed in an atomic or molecular transition, given by the difference between the upper and lower frequencies at which the intensity of radiation reaches half its maximum value.
References in periodicals archive ?
However, the aforementioned progressive optical technologies desire high-quality sources with a spectral linewidth in order of kilohertz's [1], with high degree of coherence, and low noise level.
The effect of the laser spectral linewidth broadening can be described by the well-known Schawlow-Townes formula [13]
From (1), it becomes apparent that three approaches can be used to reduce the laser spectral linewidth.
If the white frequency noise is sufficiently reduced by increasing output optical power, the spectral linewidth becomes constant.
The spectral linewidth of the laser is the only parameter of the PSD and it is characterized as full width at half maximum (FWHM).
The laser with the narrowest spectral linewidth is characterized by the highest output average power [P.
This technology, built into the V-shaped External Cavity Laser Diode Array (VECLDA), provides narrow spectral linewidth and high coherent power.
challenge this common belief that the narrow spectral linewidth and the high capital cost of lasers makes them unsuited for general illumination purposes.
The new Deep UV Mode Locked Fiber Laser features a pulse width of 10 picoseconds, a pulse frequency of 100 MHz and a spectral linewidth of 400 picometers allowing the laser to be used with today's most advanced TDI sensor technology.
However, the precision of such standards has been limited by their spectral linewidths (relative to the reference frequencies themselves).

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