Thiophenol

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thiophenol

[¦thī·ō′fē‚nȯl]
(organic chemistry)
C6H5SH A toxic, fire-hazardous, water-white liquid with a disagreeable aroma, insoluble in water, soluble in alcohol and ether, boils at 168°C; used to make pharmaceuticals. Also known as phenyl mercaptan.

Thiophenol

 

any of several organic compounds that contain a mercapto group (—SH) at the carbon atom of the aromatic ring; thiophenols are colorless, high-boiling liquids with an unpleasant odor. Thiophenols are insoluble in water but soluble in most organic solvents. The simplest thiophenol is thiophenol (phenyl mercaptan), C6H5SH, which boils at 169°C. Thiophenols are obtained by the reduction of diaryl disulfides, ArS—SAr, as well as by other methods. They are used in the synthesis of dyes and polymers, as inhibitors of radical reactions, and as stabilizers and other additives to synthetic rubbers.

References in periodicals archive ?
In the previous study it showed that B3LYP/6311+G (2d,2p) method significantly underestimates vertical gas phase ionization potentials obtained from EHOMO for monosubstituted anilines, phenols and thiophenols [30].
A mixture of thiophenol (2.7 mmol), [K.sub.2]C[O.sub.3] (0.15 mmol), and epoxide (2.6 mmol) was heated until the appearance of the first bubbles.
A mixture of epoxide 11 (1.77 g, 17 mmol), thiophenol (1.91 ml, 18.7 mmol), and DABCO (0.019 g, 0.17 mmol) in 50 ml of water was heated on an oil bath (90[degrees]C) under stirring.
A mixture of thiophenol (0.45 g, 4.1 mmol), thiirane 19 (0.53 g, 4.02 mmol), and a catalytic amount of [K.sub.2]C[O.sub.3] was heated until the appearance of first bubbles.
In continuation of our research on reactions of 3,5,8-trioxabicyclo[5.1.0]octanes with nucleophiles and antimycotic properties of the obtained products [13], in this work we have carried out the thiolysis reaction of epoxide 2 by thiophenol followed by functionalization of the resulting [beta]-hydroxysulfide 3 (Scheme 1).
The intermediate 12 was obtained from diol 10 via its oxidation with oxone followed by thiolysis of the resulting epoxide 11 with thiophenol in hot water in the presence of DABCO.
Treatment of compound 14 with thiophenol in the presence of [K.sub.2]C[O.sub.3] led to a mixture of regioisomers 15 and 16.
Galvan, "Local HSAB principle in the conjugate addition of p-Substituted thiophenols to cyclohexenone," International Journal of Quantum Chemistry, vol.
The depolymerizing effects of boosters, on the one hand, and thiophenols, on the other, differ very much when carbon black is present.