absolute stereochemistry


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absolute stereochemistry

[′ab·sə‚lüt ‚ster·ē·ō′kem·ə·strē]
(organic chemistry)
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Consideration of biogenesis and steric hinderance of sphingolipids, generally were acknowledged to determine the absolute stereochemistry of the phytosphingosine moiety.
'The absolute stereochemistry of the ester functions of fumonisin [B.sub.1]', Tetrahedon Letts.
The Circular Dichorism (CD) analysis showed positive maxima (87.0) at 245.6 nm however this information could not be found sufficient to establish the absolute stereochemistry at C-9.