aqua regia


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aqua regia

(äk`wə rē`jēə) [Lat.,=royal water], corrosive, fuming yellow liquid prepared by mixing one volume of concentrated nitric acid with three to four volumes of concentrated hydrochloric acid. It was so named by the alchemists because it dissolves gold and platinum, the "royal" metals, which do not dissolve in nitric or hydrochloric acid alone. Its fumes and yellow color are caused by reaction of nitric acid, HNO3, with hydrogen chloride, HCl, to form nitrosyl chloride, NOCl, chlorine, Cl2, and water; both chlorine and nitrosyl chloride are yellow-colored and volatile. The nitrosyl chloride further decomposes to nitric oxide, NO, and chlorine. Nitric acid is a powerful oxidizing agent (see oxidation and reductionoxidation and reduction,
complementary chemical reactions characterized by the loss or gain, respectively, of one or more electrons by an atom or molecule. Originally the term oxidation
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), but the chemical equilibriumchemical equilibrium,
state of balance in which two opposing reversible chemical reactions proceed at constant equal rates with no net change in the system. For example, when hydrogen gas, H2, and iodine gas, I2
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 for its reaction with gold, Au, only permits formation of a tiny amount of Au+3 ion, so the amount of gold dissolved in pure nitric acid is undetectable. The presence of chloride ion, Cl, allows formation of the stable chloraurate complex ioncomplex ion,
charged molecular aggregate (see ion), consisting of a metallic atom or ion to which is attached one or more electron-donating molecules. In some complex ions, such as sulfate, SO4−2
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, AuCl4. Because of the high concentration of chloride ion in aqua regia, the Au+3 is reacted almost as soon as it is formed, keeping its concentration low; this allows oxidation of more Au to Au+3, and the gold is dissolved. The gold may also react directly with the free chlorine in aqua regia, since chlorine is a powerful oxidizing agent.

Aqua Regia

 

a mixture of concentrated hydrochloric and nitric acids, usually one part nitric acid and three parts hydrochloric acid. Aqua regia is a yellow liquid with the odor of nitrogen oxides and chlorine. It has strong oxidizing properties owing to the liberation of chlorine in the reactions

3HCl + HNO3 = Cl2 + NOCl + 2H2O

2NOCl = 2NO + Cl2

Aqua regia dissolves all metals with the exception of silver, rhodium, and iridium. It even dissolves gold—hence the name “aqua regia,” given by alchemists who considered gold the king of metals. Aqua regia is used as a laboratory reagent in such processes as the refining of gold and platinum and the production of metal chlorides.

aqua regia

[¦äk·wə ′rē·jə]
(inorganic chemistry)
A fuming, highly corrosive, volatile liquid with a suffocating odor made by mixing 1 part concentrated nitric acid and 3 parts concentrated hydrochloric acid; reacts with all metals, including silver and gold.

aqua regia

a yellow fuming corrosive mixture of one part nitric acid and three to four parts hydrochloric acid, used in metallurgy for dissolving metals, including gold
References in periodicals archive ?
Chromium was only detected in nitric acid and aqua regia solutions of sample 6.
The aqua regia method of analysis is susceptible to acid interference, which makes it unreliable if used alone.
b Wet-digestion with HNO3 andH2O2 (2:1) on hot plate, c Wet-digestion with mixture of HNO3 and HClO4 on hot plate, d Wet-digestion with aqua regia on hot plate, e Wet-digestion with reverse aqua regia on hot plate, f Wet-digestion with mixture of HNO3 and H2SO4 on hot plate, g Wet-digestion with mixture of HNO3 and HF on hot plate.
The aqua regia digest results are presented in Table 2.
Soil samples are dried at low temperature, screened to 80 mesh (MSA code PRP-757), a 15 grams portion is then assayed for a multi-elements suite (MSA code IMS-136, Aqua Regia digestion, ICP-AES/MS finish).
The soil samples were digested by using aqua regia method and the aliquots obtained were analysed by using Atomic Absorption Spectrophotometer to determine the concentration of heavy metals in the samples.
Entree soil samples were also submitted to Skyline for 49 element, Aqua Regia digestion, TE-3 ICP/MS analysis.
The samples were digested with HF-HCl[O.sub.4] (Lim and Jackson 1982) and with aqua regia (Zarcinas et al.
Both labs used similar assay procedures: a 0.5g split of the -0.075mm fraction of the -80 mesh material underwent digestion with aqua regia and the liquid was analyzed for 48 elements by ICP-MS; Apart from being analyzed by ICP-MS, gold was also analyzed by fire assay with an ICP-AES finish.