Involvement of superoxide anion radical in the autoxidation
of pyrogallol and a convenient assay of superoxide dismutase.
Negative and positive assay of superoxide dismutase based on hematoxylin autoxidation
Cosgrave JP, Church DF and WA Pryor The Kinetics of Autoxidation
of Polyunsaturated Fatty Acids, Lipids 1987; 22: 299-304.
Autoxidative glycosylation is initiated by autoxidation
of the aldose/ketose sugar to a more reactive dicarbonyl sugar (glucosone), which then reacts with the protein.
The double bonds present in the fatty acid portion of plant oils have been derivatized to enable other mechanisms of crosslinking beyond autoxidation
Theoretical considerations suggest that reduced homocysteine may be capable of generating reactive oxygen species by autoxidation
in the presence of transition metals.
In addition, transition metals catalyze the autoxidation
of (bi)sulfite via sulfur trioxide anion radical S[O.
Major effects known from injection molding polyamides are chain scissions and changes of chemical structure due to autoxidation
as well as branching or cross linking as a result of macro radical recombination (Ehrenstein et al, 2004; Schnabel, 1981).
However through autoxidation
and reaction with skin enzymes, the substance is activated and becomes the closely related allergen geranial.
Carbonyls generated by autoxidation
of carbohydrates or lipid peroxidation have been implicated in advanced glycation end product (AGE) formation in tissues adversely affected by diabetes complications.
The absence of the former is desirable because C18:3 is associated with flavour deterioration and autoxidation
Much of the autoxidation
can be prevented by protecting samples from light and completing the extraction and derivatization rapidly.