benzyl

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Related to benzylic: allylic

benzyl

[′ben·zəl]
(organic chemistry)
The radical C6H5CH2- found, for example, in benzyl alcohol, C6H5CH2OH.
References in periodicals archive ?
For example, cleavage of the benzylic radicals illustrated in Schemes 6 and 7 back to their starting materials may be more important for PIP cures than for a LLDPE system.
Silane (13) has a chlorine atom bonded to an allylic group, and silane (4) has a chloride bonded to a benzylic group.
The decomposition reaction was monitored by following the benzylic protons in the (1.
Poly(VBOPE) is more stable than derivative polymers, because derivative polymers have soft side group as benzylic ether.
20 (8H) can be assigned to the protons of the benzoate group plus the benzylic protons ortho to the--C[H.
benzylic = allylic > tertiary carbon > secondary carbon > primary carbon > vinylic >> phenyl
In all cases no carbonyl product was observed by TLC analysis which indicated that this oxidant is suitable only for benzylic substrates.
Bromi-nated poly(isobutylene-co-paramethyl styrene) (BIMS, EXXPRO 3745, benzylic bromide content = 0.
With only a few benzylic bromine groups along a given BIMS chain that are interacting with CB particles, it was proposed that either a single BIMS chain is absorbed onto several filler aggregates or long loops are formed for absorbed chains.
Kakimoto, Selective Aerobic Oxidation of Benzylic Alcohols Catalyzed by Carbon-based Catalysts: A Nonmetallic Oxidation System, Angew.
In the same way, hydrogens on benzylic and allylic carbons are more easily abstracted than hydrogens found in polymers.