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Furthermore, single-molecular reactions and bimolecular reactions were modeled by Charles and Helen (2000) with the one-compartment mass balance model.
Chapter 21 - The molecular beam method: basic concepts and examples of bimolecular reaction studies.
The reaction is initiated by decomposition of the peroxide, which leads to hydrogen abstraction from the polymer, followed by bimolecular reaction of two radicals to form a crosslink in the polymer.
This is the expected result, assuming that radical termination is fast in comparison to peroxide decomposition and that crosslinking can be described adequately as an elementary bimolecular reaction (20).