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(byo͞ot'ədī`ēn), colorless, gaseous hydrocarbon. There are two structural isomers of butadiene; they differ in the location of the two carbon-carbon double bonds in the butadiene molecule. One (1,2-butadiene) has the formula CH2:C:CHCH3. The other (1,3-butadiene), often called simply butadiene, has the formula CH2:CHCH:CH2; it is used in the manufacture of synthetic rubber, latex paints, and nylon and is obtained chiefly by dehydrogenation of butane and butene obtained by cracking petroleum. Chloroprenechloroprene
or 2-chloro-1,3-butadiene,
colorless liquid organic compound used in the synthesis of neoprene and certain other rubbers. The structure of the chloroprene molecule is very similar to that of isoprene; the molecule contains two double bonds and is readily polymerized.
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 and isopreneisoprene
or 2-methyl-1,3-butadiene
, colorless liquid organic compound. It is a hydrocarbon, and is insoluble in water but soluble in many organic solvents; it boils at 34°C;. The isoprene molecule contains two double bonds.
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 are the 2-chloro- and 2-methyl-derivatives of 1,3-butadiene; they also are used in the synthesis of rubber.



(also divinyl), an organic compound, CH2=CH—CH=CH2. A colorless gas with a characteristic odor, it has a melting point of -108.9° C, a boiling point of -4.5° C, and a density of 0.650 g/cm3 at -6° C. Butadiene is not readily soluble in water but is in alcohol and kerosene. A mixture of air and butadiene, containing 1.6-10.8 percent butadiene, is explosive. Its flash point is -40° C; the maximum acceptable concentration in air is 0.1 g/m3. Butadiene adds hydrogen, the halogens, hydrogenhalides, and other electrophilic rcegents usually in the 1, 4 positions:

and also maleic anhydride to form the anhydride of tetrahydrophthalic acid (quantitative analysis reaction for determining the presence of butadiene).

Butadiene polymerizes and copolymerizes easily to form valuable elastomers (butadiene rubbers, butadiene-acrylonitrile rubbers, butadiene-styrene rubbers, vinyl pyridine rubbers).

The most promising industrial method of producing butadiene is catalytic dehydration of normal butane and butenes contained in the gases of the oil-refining process and in byproduct gases; the process is carried out in one or two stages. Methods are being developed for the oxidative dehydration of normal butane and butylenes. This will make it possible to substantially increase the yield of butadiene. It is also produced by passing the vapor of ethyl alcohol over a mixed dehydration-dehydrogenation catalyst (the S. V. Lebedev method). Butadiene is a byproduct of the production of ethylene and other olefins of gases formed during the pyrolysis of petroleum products.


Iukel’son, I. I. Tekhnologiia osnovnogo organicheskogo sinteza. Moscow, 1968.
References in periodicals archive ?
The partnership will leverage Genomatica's proprietary technologies and intellectual property for producing butadiene, Versalis' extensive expertise in catalysis process development and process engineering scale-up and market applications of butadiene derivatives, as well as Novamont's experience in renewable feedstocks.
In terms of demand, ABS is predicted to be the country's fastest growing butadiene segment, due to the demands from the household appliances, electronic and automotive sectors, all of which are expected to exhibit impressive growth in the lead-up to 2020.
Moderate flaring of the olefins cracker signalled the start of the Butadiene 3 overhaul.
The joint venture will make and market butadiene rubber used in tires.
The Commissions investigation also showed that the combination of Basells and the butadiene plants activities was not likely to create competition concerns in view of the presence of alternative and competing sources of butadiene supply in Western Europe.
OSHA determined that the March explosion took place when a runaway chemical reaction occurred in a tank containing an unknown quantity of butadiene that burst the 12,000-gal.
Butadiene, a compound widely used in the production of synthetic rubber and other resins, causes cancer in many organs in both rats and mice, but mice are about 1,000 times more sensitive to its carcinogenic effects than rats.
Companies tailor ABS for its various uses by adjusting the amount, size and structure of the particles of butadiene, a rubber mixed in to make ABS less brittle.
The vulcanized rubber composition comprises a phase (SBR phase) comprising a styrene butadiene rubber being incompatible with a butadiene rubber and silica and a phase (BR phase) comprising a butadiene rubber and silica, wherein the SBR phase and the BR phase are incompatible with each other, an abundance ratio a of silica in the SBR phase after vulcanization satisfies 0.
These accomplishments represent a remarkable milestone for the rubber industry, by enabling an improved technological and sustainability footprint; and to the broader industry for butadiene, one of the most widely-used chemicals in the world, with over ten million tons produced per year.