catalytic converter


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internal-combustion engine

internal-combustion engine, one in which combustion of the fuel takes place in a confined space, producing expanding gases that are used directly to provide mechanical power. Such engines are classified as reciprocating or rotary, spark ignition or compression ignition, and two-stroke or four-stroke; the most familiar combination, used from automobiles to lawn mowers, is the reciprocating, spark-ignited, four-stroke gasoline engine. Other types of internal-combustion engines include the reaction engine (see jet propulsion, rocket), and the gas turbine. Engines are rated by their maximum horsepower, which is usually reached a little below the speed at which undue mechanical stresses are developed.

Reciprocating Engines

The most common internal-combustion engine is the piston-type gasoline engine used in most automobiles. The confined space in which combustion occurs is called a cylinder. The cylinders are now usually arranged in one of four ways: a single row with the centerlines of the cylinders vertical (in-line engine); a double row with the centerlines of opposite cylinders converging in a V (V-engine); a double zigzag row somewhat similar to that of the V-engine but with alternate pairs of opposite cylinders converging in two Vs (W-engine); or two horizontal, opposed rows (opposed, pancake, flat, or boxer engine). In each cylinder a piston slides up and down. One end of a connecting rod is attached to the bottom of the piston by a joint; the other end of the rod clamps around a bearing on one of the throws, or convolutions, of a crankshaft; the reciprocating (up-and-down) motions of the piston rotate the crankshaft, which is connected by suitable gearing to the drive wheels of the automobile. The number of crankshaft revolutions per minute is called the engine speed. The top of the cylinder is closed by a metal cover (called the head) bolted onto it. Into a threaded aperture in the head is screwed the spark plug, which provides ignition.

Two other openings in the cylinder are called ports. The intake port admits the air-gasoline mixture; the exhaust port lets out the products of combustion. A mushroom-shaped valve is held tightly over each port by a coil spring, and a camshaft rotating at one-half engine speed opens the valves in correct sequence. A pipe runs from each intake port to a carburetor or injector, the pipes from all the cylinders joining to form a manifold; a similar manifold connects the exhaust ports with an exhaust pipe and noise muffler. A carburetor or fuel injector mixes air with gasoline in proportions of weight varying from 11 to 1 at the richest to a little over 16 to 1 at the leanest. The composition of the mixture is regulated by the throttle, an air valve in the intake manifold that varies the flow of fuel to the combustion chambers of the cylinders. The mixture is rich at idling speed (closed throttle) and at high speeds (wide-open throttle), and is lean at medium and slow speeds (partly open throttle).

The other main type of reciprocating engine is the diesel engine, invented by Rudolf Diesel and patented in 1892. The diesel uses the heat produced by compression rather than the spark from a plug to ignite an injected mixture of air and diesel fuel (a heavier petroleum oil) instead of gasoline. Diesel engines are heavier than gasoline engines because of the extra strength required to contain the higher temperatures and compression ratios. Diesel engines are most widely used where large amounts of power are required: heavy trucks, locomotives, and ships.

Rotary Engines

The most successful rotary engine is the Wankel engine. Developed by the German engineer Felix Wankel in 1956, it has a disk that looks like a triangle with bulging sides rotating inside a cylinder shaped like a figure eight with a thick waist. Intake and exhaust are through ports in the flat sides of the cylinder. The spaces between the sides of the disk and the walls of the cylinder form combustion pockets. During a single rotation of the disk each pocket alternately grows smaller, then larger, because of the contoured outline of the cylinder. This provides for compression and expansion. The engine runs on a four-stroke cycle.

The Wankel engine has 48% fewer parts and about a third the bulk and weight of a reciprocating engine. Its main advantage is that advanced pollution control devices are easier to design for it than for the conventional piston engine. Another advantage is that higher engine speeds are made possible by rotating instead of reciprocating motion, but this advantage is partially offset by the lack of torque at low speeds, leading to greater fuel consumption.

Engine Operation

The Four-Stroke Cycle

In most engines a single cycle of operation (intake, compression, power, and exhaust) takes place over four strokes of a piston, made in two engine revolutions. When an engine has more than one cylinder the cycles are evenly staggered for smooth operation, but each cylinder will go through a full cycle in any two engine revolutions. When the piston is at the top of the cylinder at the beginning of the intake stroke, the intake valve opens and the descending piston draws in the air-fuel mixture.

At the bottom of the stroke the intake valve closes and the piston starts upward on the compression stroke, during which it squeezes the air-fuel mixture into a small space at the top of the cylinder. The ratio of the volume of the cylinder when the piston is at the bottom to the volume when the piston is at the top is called the compression ratio. The higher the compression ratio, the more powerful the engine and the higher its efficiency. However, in order to accommodate air pollution control devices, manufacturers have had to lower compression ratios.

Just before the piston reaches the top again, the spark plug fires, igniting the air-fuel mixture (alternatively, the heat of compression ignites the mixture). The mixture on burning becomes a hot, expanding gas forcing the piston down on its power stroke. Burning should be smooth and controlled. Faster, uncontrolled burning sometimes occurs when hot spots in the cylinder preignite the mixture; these explosions are called engine knock and cause loss of power. As the piston reaches the bottom, the exhaust valve opens, allowing the piston to force the combustion products—mainly carbon dioxide, carbon monoxide, nitrogen oxides, and unburned hydrocarbons—out of the cylinder during the upward exhaust stroke.

The Two-Stroke Cycle

The two-stroke engine is simpler mechanically than the four-stroke engine. The two-stroke engine delivers one power stroke every two strokes instead of one every four; thus it develops more power with the same displacement, or can be lighter and yet deliver the same power. For this reason it is used in lawn mowers, chain saws, small automobiles, motorcycles, and outboard marine engines.

However, there are several disadvantages that restrict its use. Since there are twice as many power strokes during the operation of a two-stroke engine as there are during the operation of a four-stroke engine, the engine tends to heat up more, and thus is likely to have a shorter life. Also, in the two-stroke engine lubricating oil must be mixed with the fuel. This causes a very high level of hydrocarbons in its exhaust, unless the fuel-air mixture is computer calculated to maximize combustion. A highly efficient, pollution-free two-stroke automobile engine is currently being developed by Orbital Engineering, under arrangements with all the U.S. auto makers.

Cooling and Lubrication of Engines

Most small two-stroke engines are air-cooled. Air flows over cooling fins around the outside of the cylinder and head, either by the natural motion of the vehicle or from a fan. Many aircraft four-stroke engines are also air-cooled; larger engines have the cylinders arranged radially so that all cylinders are directly in the airstream. Most four-stroke engines, however, are water-cooled. A water jacket encloses the cylinders; a water pump forces water through the jacket, where it draws heat from the engine. Next, the water flows into a radiator where the heat is given off to the air; it then moves back into the jacket to repeat the cycle. During warm-up a thermostatic valve keeps water from passing to the radiator until optimum operating temperatures are attained.

Four-stroke engines are lubricated by oil from a separate oil reservoir, either in the crankcase, which is a pan attached to the underside of the engine, or in an external tank. In an automobile engine a gear pump delivers the oil at low pressure to the bearings. Some bearings may depend on oil splashed from the bottom of the crankcase by the turning crankshaft. In a two-stroke engine the lubricating oil is mixed with the fuel.

Environmental Considerations in Engine Design

In order to meet U.S. government restrictions on exhaust emissions, automobile manufacturers have had to make various modifications in the operation of their engines. For example, to reduce the emission of nitrogen oxides, one modification involves sending a certain proportion of the exhaust gases back into the air-gasoline mixture going into the engine. This cuts peak temperatures during combustion, lessening the amount of nitrogen oxides produced. In the stratified charge piston engine two separate air-fuel mixtures are injected into the engine. A small, rich mixture that is easily ignited is used to ignite an exceptionally lean mixture that drives the piston. This results in much more efficient burning of the gasoline, further reducing emissions. Another device, the catalytic converter, is connected to the exhaust pipe; exhaust gases travel over bars or pellets coated with certain metals that promote chemical reactions, reducing nitrogen oxide and burning hydrocarbons and carbon monoxide.

For many years engine knock (rapid uncontrolled burning that sometimes occurs when hot spots in the cylinder preignite the mixture causing loss of power) was fought through the introduction of lead into gasoline. However, concern over air pollution and lead's destructive effect on catalytic converters forced its removal. The state of California, with the worst air pollution in the United States, has instituted a series of measures designed to reduce automobile emissions; these include special gasolines, different air-gas mixtures, and higher compression ratios. All cars, trucks, and gasolines sold in California must comply with these regulations.

Evolution of the Internal-Combustion Engine

The first person to experiment with an internal-combustion engine was the Dutch physicist Christian Huygens, about 1680. But no effective gasoline-powered engine was developed until 1859, when the French engineer J. J. Étienne Lenoir built a double-acting, spark-ignition engine that could be operated continuously. In 1862 Alphonse Beau de Rochas, a French scientist, patented but did not build a four-stroke engine; sixteen years later, when Nikolaus A. Otto built a successful four-stroke engine, it became known as the “Otto cycle.” The first successful two-stroke engine was completed in the same year by Sir Dougald Clerk, in a form which (simplified somewhat by Joseph Day in 1891) remains in use today. George Brayton, an American engineer, had developed a two-stroke kerosene engine in 1873, but it was too large and too slow to be commercially successful.

In 1885 Gottlieb Daimler constructed what is generally recognized as the prototype of the modern gas engine: small and fast, with a vertical cylinder, it used gasoline injected through a carburetor. In 1889 Daimler introduced a four-stroke engine with mushroom-shaped valves and two cylinders arranged in a V, having a much higher power-to-weight ratio; with the exception of electric starting, which would not be introduced until 1924, most modern gasoline engines are descended from Daimler's engines.

Bibliography

See E. F. Obert, Internal Combustion Engine (1950); C. F. Taylor and E. S. Taylor, The Internal Combustion Engine (1984); and J. B. Heywood, Internal Combustion Engine Fundamentals (1988).

The Columbia Electronic Encyclopedia™ Copyright © 2022, Columbia University Press. Licensed from Columbia University Press. All rights reserved.

catalytic converter

[¦kad·əl¦id·ik kən′vərd·ər]
(chemical engineering)
A device that is fitted to the exhaust system of an automotive vehicle and contains a catalyst capable of converting potentially polluting exhaust gases into harmless or less harmful products.
McGraw-Hill Dictionary of Scientific & Technical Terms, 6E, Copyright © 2003 by The McGraw-Hill Companies, Inc.

Catalytic converter

An aftertreatment device used for pollutant removal from automotive exhaust. Since the 1975 model year, increasingly stringent government regulations for the allowable emission levels of carbon monoxide (CO), hydrocarbons (HC), and oxides of nitrogen (NOx) have resulted in the use of catalytic converters on most passenger vehicles sold in the United States. The task of the catalytic converter is to promote chemical reactions for the conversion of these pollutants to carbon dioxide, water, and nitrogen.

For automotive exhaust applications, the pollutant removal reactions are the oxidation of carbon monoxide and hydrocarbons and the reduction of nitrogen oxides. Metals are the catalytic agents most often employed for this task. Small quantities of these metals, when present in a highly dispersed form (often as individual atoms), provide sites upon which the reactant molecules may interact and the reaction proceed.

Two types of catalyst systems, oxidation and three-way, are found in automotive applications. Oxidation catalysts remove only CO and HC, leaving NOx unchanged. Platinum and palladium are generally used as the active metals in oxidation catalysts. Three-way catalysts are capable of removing all three pollutants simultaneously, provided that the catalyst is maintained in a “chemically correct” environment that is neither overly oxidizing nor reducing. In both oxidation and three-way catalyst systems, the production of undesirable reaction products, such as sulfates and ammonia, must be avoided.

Maintaining effective catalytic function over long periods of vehicle operation is often a major problem. Catalytic activity will deteriorate due to two causes, poisoning of the active sites by contaminants, such as lead and phosphorus, and exposure to excessively high temperatures. To achieve efficient emission control, it is thus paramount that catalyst-equipped vehicles be operated only with lead-free fuel and that proper engine maintenance procedures be followed. See Automotive engine

McGraw-Hill Concise Encyclopedia of Engineering. © 2002 by The McGraw-Hill Companies, Inc.

catalytic converter

a device using three-way catalysts to reduce the obnoxious and poisonous components of the products of combustion (mainly oxides of nitrogen, carbon monoxide, and unburnt hydrocarbons) from the exhausts of motor vehicles
Collins Discovery Encyclopedia, 1st edition © HarperCollins Publishers 2005
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The work builds on 2016 research in which groups led by Datye and Yong Wang--who holds a joint appointment in WSU's School of Chemical Engineering and Bioengineering and the Pacific Northwest National Laboratory--found a novel way to trap and stabilize individual platinum atoms on the surface of cerium oxide, a commonly-used component in emissions control catalytic converters. The so-called single-atom catalyst uses platinum more efficiently while remaining stable at high temperatures.
On the other hand, with the evolution of technology, the automobile industry is shifting towards electric vehicles, which will act as a restraint for the global industrial catalytic converters market.
Catalytic converters are prized by thieves who rip out the devices because they contain the precious metals platinum and palladium.
Eastern is a manufacturer and suppliers of catalytic converters to the aftermarket.
"Police would also like to hear from anyone who has been offered a cheap catalytic converter for sale to make contact."
Dr Benjamin Kingsbury, research associate at Imperial College London's department of chemical engineering, has advanced the existing manufacturing process of catalytic converters to improve the structure of the ceramic block's microscopic channels (right).
A CHARITY in the Vale of Glamorgan has been hit by thieves who stole the valuable catalytic converter from a minibus used by pensioners.
"Thieves can cut the catalytic converter from the exhaust pipe of a parked car.
"I got out and looked underneath it, and sure enough, the catalytic converter was gone."
HE WAS the man who led the development of the catalytic converter only to be ousted in a boardroom coup.