chair conformation
chair conformation
[′cher ‚kän·fər‚mā·shən] (physical chemistry)
McGraw-Hill Dictionary of Scientific & Technical Terms, 6E, Copyright © 2003 by The McGraw-Hill Companies, Inc.
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Ab initio calculations for 1 and 3 predict that twist-boat conformation is lower in free energy than the chair conformation, whereas chair (ax) form is found to be more stable for 2.
This is an elegant demonstration of how NMR helps to visualize the pyranose cycle chair conformation.
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