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Eigenvalue (quantum mechanics)
If an equation containing a variable parameter possesses nontrivial solutions only for certain special values of the parameter, these solutions are called eigenfunctions and the special values are called eigenvalues.
The eigenfunction-eigenvalue relation is of particular importance in quantum mechanics because of its prominence in the equations which relate the mathematical formalism of the theory with physical results. See Quantum mechanics
(or characteristic value). An eigenvalue of a linear transformation or operator A is a number λ for which there exists a nonzero vector x such that Ax = λx; the vector x is called an eigenvector, or characteristic vector. Thus, the eigenvalues of a differential operator L(y) with given boundary conditions are numbers X for which the equation L(y) = λy has a nonzero solution that satisfies the boundary conditions. For example, if the operator L(y) has the form -y”, then numbers of the form λn = n2, where n is a natural number, are eigenvalues of the operator under the boundary conditions y (0) = y (π) = 0, since the functions yn = sin nx satisfy the equation - yn = n2y with the indicated boundary conditions. If, however, λ + n2 for any natural n, then only the function y(x) = 0 satisfies the equation –y” = λy under the same boundary conditions. Eigenvalues of linear operators are of importance in many problems in mathematics, mechanics, and physics—in problems, for example, in analytic geometry, algebra, the theory of vibrations, and quantum mechanics.
The eigenvalues of the matrix A = ║aik║, where i, k = 1, 2, . . . , n, are the eigenvalues of the linear transformation on an n-dimensional complex space that corresponds to A. The eigenvalues can also be defined as the roots of the equation det(A - λE) = 0, where E is the unit matrix—that is, the roots of the equation
which is called the characteristic equation of the matrix. Since these numbers are the same for the similar matrices A and B’XAB where B is a nonsingular matrix, they characterize properties of the linear transformation that are independent of the choice of coordinate system. To each root λ, of equation (*) there corresponds a vector xi ≠ 0 (an eigenvector) such that Axi = λixi. If all the eigenvalues are distinct, then the set of eigenvectors may be chosen as the basis of the vector space. With respect to this basis, the linear transformation is described by the diagonal matrix
Every matrix A with distinct eigenvalues can be represented in the form C–1ʌC. If A is a Hermitian matrix, then its eigenvalues are real, the eigenvectors are orthogonal, and there exists a unitary matrix that can be chosen as C. The absolute value of every eigenvalue of a unitary matrix is equal to 1. The sum of the eigenvalues of a matrix is equal to the sum of its diagonal elements—that is, to the trace of the matrix. Knowledge of the eigenvalues of a matrix plays an important role in the investigation of the convergence of certain approximate methods of solving systems of linear equations.