, characteristic infrared absorption of methylsulfones and crystal structures of selected aromaticsulfones.
This led to a model called negative hyperconjugation
that was based on p oxygen orbitals interacting with silicon sigma antibonding orbitals.
effects on RDX conformation were evaluated because of the lone pair of electrons on the atrazine ring nitrogens.
This would donate a charge through hyperconjugation
and by the inductive effect, thus concentrating the charge density on nitrogen and sulfur atoms--thereby increasing their adsorption at the anodic sites of the metal.
It was found that the mesomeric and the hyperconjugation effects have a strong influence on the antibacterial activity.
This might come from the hyperconjugation effect which created by the methyl group of the 3-methylbenzene substituent Scheme 3.
This result is consistent with the concept that the stabilization of aliphatic and alicyclic carbanions is largely dependent on anionic hyperconjugation, involving the interaction between the electronic "lone pair" and antibonding C-H and C-C [[sigma].
This tends to suggest fluorine hyperconjugation with a transfer of electron density from the [sigma](C-C) orbitals to the [[sigma].
Then, Pophristic looked at the other known influence on ethane's twisting--a quantum mechanical effect known as hyperconjugation.
Hyperconjugation, not steric effects, makes staggered ethane stable, they conclude.
Discussing various electronic effects, particularly stereoelectronic effects, including hyperconjugation
, negative hyperconjugation
, the Bohlmann and anomeric effects, and how and why these cause changes in structures and properties of molecules
They have been using spin density calculations in free radicals to show hyperconjugation
and resonance phenomena.