caustic potash, KOH, a strong alkali; colorless crystals. Density, 2.12 g/cm3 (25°C); melting point, 380°C.
Potassium hydroxide is readily soluble in water (97 g per 100 g H2O at 0°C; 112 g at 20°C), liberating a considerable amount of heat. Potassium hydroxide is produced commercially in the form of an opaque solid white mass containing 90–92 percent KOH (representing a mixture of KOH and KOH·H2O). In the air, potassium hydroxide absorbs H2O and C02 and deliquesces, gradually converting to potassium carbonate K2C03. Potassium hydroxide has a destructive effect on skin, paper, wool, silk, and other organic materials; it causes severe burns on human skin and is particularly dangerous to the eyes. Safety goggles and rubber gloves must be worn when working with it. Potassium hydroxide is obtained by the electrolysis of calcium chloride solutions. Potassium hydroxide is used in the manufacture of liquid soaps, as a source material in the preparation of potassium salts, in alkaline batteries, and as a laboratory reagent.